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Crown Inclusion Compounds with 3,4-Diamino-1,2,5-Oxadiazole. X-Ray Structures of Its 1:1 Inclusion Complexes with 15-Crown-5 and Benzo-15-crown-5

✍ Scribed by Roman Luboradzki; Janusz Lipowski; Yurii A. Simonov; Marina S. Fonari; Edward V. Ganin; Arkadii A. Yavolovskii


Book ID
110297614
Publisher
Springer Netherlands
Year
2001
Tongue
English
Weight
129 KB
Volume
40
Category
Article
ISSN
0923-0750

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A luminescent bicapped trinuclear copper(I) acetylide complex, [Cu 3 (m-dppm) 3 (m 3 -h 1 -C C-benzo-15-crown-5) 2 ]PF 6 , has been synthesized and its photophysical properties studied. Sodium ion-binding by the crown ether cavity has been studied by electrospray ionization-mass spectrometry and emi