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Crossed beam study of the reaction H+2 + D2 → D2H+ + H

✍ Scribed by P.M. Hierl; Z. Herman


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
573 KB
Volume
50
Category
Article
ISSN
0301-0104

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The kinematics of the reaction H;(Dz, Hz)D~H+were studied over the initial relative energy range from 0.22 to 5.21 eV For ground state reactants. The reaction was found fo proceed via a direct mechanism at all energies studied. Indirect evidence suggests, however, that substantial comples formation

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A crossed beam study of the title reaction if reported, from 0.45 to 7.8 eV. The reaction is predominantly transkxtioionally endothermic. At the lowest energy, there is evidence for two reactlon paths: a long-range electron transfer and an titimate coihsion mth electron transfer. Branching ratios fo