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Cross-Metathesis of Vinylsilanes with Styrene Catalyzed by Ruthenium−Carbene Complexes

✍ Scribed by Pietraszuk, Cezary; Marciniec, Bogdan; Fischer, Helmut

Book ID
117995700
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
195 KB
Volume
19
Category
Article
ISSN
0276-7333

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✍ Zenon Foltynowicz; Bogdan Marciniec 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 63 KB 👁 2 views

## In the cross-metathesis reaction of tri(methyl, ethoxy)vinylsilanes with propene and/or 1-butene catalyzed by RuCl 2 (PPh 3 ) 3 activated in benzene at 115-130 °C, a series of l-alkenylsilanes of general formula CH 3 (CH 2 ) m CH = CHSiMe 3 Ϫ n (OEt) n , where m = 0, 1, and n = 0-3 (1-silyl-1-a