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ChemInform Abstract: Cross-Metathesis of Vinylsilanes with Styrene Catalyzed by Ruthenium—Carbene Complexes.

✍ Scribed by Cezary Pietraszuk; Bogdan Marciniec; Helmut Fischer


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Ruthenium-Catalyzed Cross-Metathesis of
✍ Zenon Foltynowicz; Bogdan Marciniec 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 63 KB 👁 1 views

## In the cross-metathesis reaction of tri(methyl, ethoxy)vinylsilanes with propene and/or 1-butene catalyzed by RuCl 2 (PPh 3 ) 3 activated in benzene at 115-130 °C, a series of l-alkenylsilanes of general formula CH 3 (CH 2 ) m CH = CHSiMe 3 Ϫ n (OEt) n , where m = 0, 1, and n = 0-3 (1-silyl-1-a