Cr−CO Photodissociation in Cr(CO) 6 : Reassessment of the Role of Ligand-Field Excited States in the Photochemical Dissociation of Metal−Ligand Bonds
✍ Scribed by Pollak, C.; Rosa, A.; Baerends, E. J.
- Book ID
- 127277826
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 178 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures