varied iteratively in the refinement until an equivalent isotropic displacement factor comparable with that at the other positions resulted. For each ring position in the disorder model so obtained the C:P ratio was fixed, an anisotropic displacement factor refined together with the atomic positions
Cp′2TiS5O und Cp′2TiOS5 - isomere Titanocenkomplexe mit zwei neuartigen S-O-Chelatliganden (Cp′ = η5-CH3C5H4)
✍ Scribed by Prof. Dr. Ralf Steudel; Dipl.-Chem. Andreas Prenzel; Prof. Dr. Joachim Pickardt
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 384 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,
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