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Cover Picture: Artificial Metalloenzymes for Enantioselective Catalysis Based on the Noncovalent Incorporation of Organometallic Moieties in a Host Protein (Chem. Eur. J. 13/2005)

✍ Scribed by Thomas R. Ward


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
313 KB
Volume
11
Category
Article
ISSN
0947-6539

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Artificial Metalloenzymes for Enantiosel
✍ Thomas R. Ward 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 619 KB

## Abstract Enzymatic and homogeneous catalysis offer complementary means to produce enantiopure products. Incorporation of achiral, biotinylated aminodiphosphine–rhodium complexes in (strept)avidin affords enantioselective hydrogenation catalysts. A combined chemogenetic procedure allows the optim