Artificial Metalloenzymes for Enantiosel
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Thomas R. Ward
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Article
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2005
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John Wiley and Sons
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English
β 619 KB
## Abstract Enzymatic and homogeneous catalysis offer complementary means to produce enantiopure products. Incorporation of achiral, biotinylated aminodiphosphineβrhodium complexes in (strept)avidin affords enantioselective hydrogenation catalysts. A combined chemogenetic procedure allows the optim