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Artificial Metalloenzymes for Enantioselective Catalysis Based on the Noncovalent Incorporation of Organometallic Moieties in a Host Protein

✍ Scribed by Thomas R. Ward


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Artificial Metalloenzymes for Enantiosel
✍ Thomas R. Ward πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 619 KB

## Abstract Enzymatic and homogeneous catalysis offer complementary means to produce enantiopure products. Incorporation of achiral, biotinylated aminodiphosphine–rhodium complexes in (strept)avidin affords enantioselective hydrogenation catalysts. A combined chemogenetic procedure allows the optim