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Covalent modification of carbon surfaces by grafting of functionalized aryl radicals produced from electrochemical reduction of diazonium salts

✍ Scribed by Delamar, Michel; Hitmi, Rachid; Pinson, Jean; Saveant, Jean Michel

Book ID
120470334
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
287 KB
Volume
114
Category
Article
ISSN
0002-7863

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Modification of carbon fiber surfaces by
Modification of carbon fiber surfaces by electrochemical reduction of aryl diazonium salts: Application to carbon epoxy composites
✍ M. Delamar; G. DΓ©sarmot; O. Fagebaume; R. Hitmi; J. Pinsonc; J.-M. SavΓ©ant πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 713 KB

Electrochemical reduction of aryl diazonium salts on carbon fibers both in aprotic and in aqueous acidic solutions leads to the grafting of the aryl group on the carbon surfaces. In acidic medium the grafting of 4-nitrophenyl groups occurs simultaneously with the reduction to 4-aminophenyl groups wh