Covalent Modification of Carbon Surfaces by Aryl Radicals Generated from the Electrochemical Reduction of Diazonium Salts
✍ Scribed by Allongue, Philippe; Delamar, Michel; Desbat, Bernard; Fagebaume, Olivier; Hitmi, Rachid; Pinson, Jean; Savéant, Jean-Michel
- Book ID
- 120056409
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 293 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Electrochemical reduction of aryl diazonium salts on carbon fibers both in aprotic and in aqueous acidic solutions leads to the grafting of the aryl group on the carbon surfaces. In acidic medium the grafting of 4-nitrophenyl groups occurs simultaneously with the reduction to 4-aminophenyl groups wh
Aryl radicals generated by electrochemical reduction of aryl halides in aprotic medium react with styrene and its derivatives to give arylated addition compounds. The electrochemical reduction of aryl halides offers a convevient means to generate aryl radicals in a controlled manner through the clea
In this study, pyridine, quinoline and phenanthroline molecules were covalently bonded to glassy carbon (GC) electrode surfaces for the first time using the diazonium modification method. Then, the complexation ability of the modified films with ruthenium metal cations was investigated. The derivati