Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent
β Scribed by Krief, Alain; Laval, Anne-Marie
- Book ID
- 115315437
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 635 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0009-2665
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π SIMILAR VOLUMES
Treatment of sulfur-substituted aromatic lactams with carbonyl compounds in the presence of samarium(II) diiodide was found to undergo novel tandem desulfurization and reductive coupling reactions to generate a-hydroxyalkylated lactams in high yield. Stereochemistry of the coupling products was rese
Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O1 to yield homoallylic alcohols. ## In a previous paper we reported the Pd(O)-catalyzed reduction of allylic acetates with Sm12 and Z-propanol.