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Coupling of aryl Grignard reagents by electron transfer to unsaturated 1,4-dihalo compounds

✍ Scribed by Taylor, Stephen K.; Bennett, Stephen G.; Heinz, Karl J.; Lashley, Lauren K.


Book ID
125959568
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
439 KB
Volume
46
Category
Article
ISSN
0022-3263

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Enantioselective Copper-Catalyzed 1,4-Ad
✍ Maurus Spescha; Grety Rihs 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 693 KB

The enantioselective copper-catalyzed 1,4-addition of Grignard reagents to a$-unsaturated carbonyl compounds was studied with the following Cu' compounds as catalyst precursor and 1,2 : 5,6-di-0 -isopropylidene-3thio-a -o-glucofuranose (Hsiig) as chiral ligand: CuI, iodo[bis(dibutylsulfide)]copper(I