Counting Spins with a New Spin Echo Double Resonance
β Scribed by Tom S. Cull; J.M. Joers; Terry Gullion; R.E. Norberg; Mark S. Conradi
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 140 KB
- Volume
- 133
- Category
- Article
- ISSN
- 1090-7807
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β¦ Synopsis
In traditional spin echo double resonance (SEDOR), the echo amplitude M is decreased when the observed spins S are flipped by pi together with the pi refocusing pulse on the observed spins I; the dependence on tau is then determined. In the new version of SEDOR, the echo amplitude is measured as a function of the S spin flip angle theta at a constant pulse spacing tau. The analysis is simple and powerful for long tau, where the strong collision limit applies. There, the variation of M with theta can be fit, yielding the number n of spins S to which each spin I is coupled. Data from amorphous silicon with 1H and 2D show the described effect. A MAS version of the new method is used on multiply labeled alanine and urea, with results in good agreement with the predictions for n = 2, as expected. By Fourier transforming M with respect to the flip angle theta, a stick spectrum results; the largest numbered non-vanishing stick yields the number n of spins S coupled to each spin I. Simulations are presented for an n = 2 system. The present technique is compared to the multiple-quantum spin-counting method. Copyright 1998 Academic Press.
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