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Counter-ion radius dependence of the mixed-valence state in MX chain platinum complexes

โœ Scribed by Nobuyuki Matsushita; Hiroshi Kitagawa; Tadaoki Mitani


Book ID
116136504
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
202 KB
Volume
71
Category
Article
ISSN
0379-6779

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Calculations of the resonance Raman excitation profiles for the v, band and its overtones have been performed for the linearchain mixed-valence platinum complex [Pt(en)\*] [Pt(en)zBr,]Br, It is found that the Pt'"-Br bond length increases by 0.075 A in the intervalence state. A satisfactory fit to t