Coumarins of the genusLedum
โ Scribed by M. V. Klokova; E. A. Serykh; T. P. Berezovskaya
- Book ID
- 112377630
- Publisher
- Springer
- Year
- 1982
- Tongue
- English
- Weight
- 67 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-3130
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๐ SIMILAR VOLUMES
13C NMR data for several simple coumarins are reported. The ysvn effect of a 5-methoxy substituent on the C-4 chemical shift was observed and measured. The effects of an 8-iodo substituent on the chemical shifts of the carbons of the coumarinic skeleton are discussed.
The ether extract of tbe root of Pteryxia terebinthina var. californica (Coult. and Rose) Mathias, in addition to osthol, anomalin (I), and pteryxin (111), afforded two new coumarins: 3'(S),4'(S)-3'-angeloyloxy-4'-acetoxy-~',4'-dihydroseselin (IV) and ## 3'(S),4'(S)-3'-angeloyloxy-4'-senecioyloxy-3
## Abstract ^13^C NMR data of nineteen coumarins, twelve of which bear a prenyl (isoprenoid) sideโchain at Cโ3, are reported and compared with those of the Cโ3 unsubstituted compounds. Unlike the linear isomers, no ฮณโeffect is observed in the corresponding angular derivatives; this is proposed as s