## Abstract The total synthesis of (__E__)‐Suberenol (1) was carried out under the conditions of palladium‐catalysed Heck condensation. Two other new coumarins, (__E__)‐7‐methoxy‐6‐(3‐methyl‐1,3‐butadienyl)coumarin [(__E__)‐suberodiene] (3) and (__E__)‐7‐methoxy‐6‐(3‐methyl‐1‐butenyl)coumarin [(__E
Coumarins IV. Coumarins of pteryxia terebinthina. Structures of two new coumarins, isopteryxin and calipteryxin
✍ Scribed by B. Eichstedt Nielsen; T. O. Soine
- Publisher
- John Wiley and Sons
- Year
- 1967
- Tongue
- English
- Weight
- 446 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3549
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✦ Synopsis
The ether extract of tbe root of Pteryxia terebinthina var. californica (Coult. and Rose) Mathias, in addition to osthol, anomalin (I), and pteryxin (111), afforded two new coumarins: 3'(S),4'(S)-3'-angeloyloxy-4'-acetoxy-~',4'-dihydroseselin (IV) and
3'(S),4'(S)-3'-angeloyloxy-4'-senecioyloxy-3',4'-dihydroseselin (V).
These coumarins are provisionally named isopteryxin and calipteryxin, respectively.
N KEEPING with a n interest in naturally oc-anomala La11 b y Hata et al., and its structure de-I curring coumarins (1) and prompted by the termination as the 3',4'-diangelate ester of 3',4'recent isolation of anomalin (I) from Angelica dihydroxy-3',4'-dihydroseselin (II), the present
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