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Natural product chemistry, 139. Synthesis of the natural coumarins (E)-suberenol, cyclobisuberodiene and two other related new coumarins

✍ Scribed by Reisch, Johannes ;Herath, H. M. T. Bandara ;Kumar, N. Savitri

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 271 KB
Volume: 1990
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1990199001171

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✦ Synopsis

Abstract

The total synthesis of (E)‐Suberenol (1) was carried out under the conditions of palladium‐catalysed Heck condensation. Two other new coumarins, (E)‐7‐methoxy‐6‐(3‐methyl‐1,3‐butadienyl)coumarin [(E)‐suberodiene] (3) and (E)‐7‐methoxy‐6‐(3‐methyl‐1‐butenyl)coumarin [(E)‐suberenene] (4) and cyclobisuberodiene (2) were synthesised from (E)‐suberenol.

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