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Corrosion inhibitors performance for mild steel in CO2 containing solutions

✍ Scribed by G. Zavala Olivares; M. J. Hernández Gayosso; J. L. Mora Mendoza


Publisher
John Wiley and Sons
Year
2007
Tongue
German
Weight
511 KB
Volume
58
Category
Article
ISSN
0947-5117

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✦ Synopsis


Abstract

The Electrochemical Impedance Spectroscopy (EIS), was used to evaluate and compare the behavior of three different corrosion inhibitors: quaternary amine (QA), oleic imidazoline (OI) and amino coco propionic acid (ACP), on the corrosion of mild steel in 3% NaCl solutions, saturated with CO~2~ gas, under static conditions. Two pH values: 3.8 and 5.5 were considered. Under the conditions considered in this work, the results indicated film formation at the metal surface, probable due to the formation of iron carbonate. This condition modified the values of the resistance and double layer capacitance of the system. In general terms, the ACP inhibitor exhibited better performance, compared to the QA and OI. During the impedance measurements with OI and ACP, some deviations were observed at high frequencies, indicating probably that the inhibitors adsorption occurs in different way to the QA inhibitor and the amine adsorption is weaker than the other two inhibitors adsorption.


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