The localised corrosion resistance (pitting and crevice corrosion) of two high alloy stainless steels, namely superduplex (SD) and superaustenitic (SA), has been studied in chloride-fluoride solutions at pH values ranging from 2 to 6.5. The pitting potential (E pit ) and crevice potential (E cre ) h
Corrosion Behaviour of Manganese-Containing Stainless Steels. III. Their susceptibility towards pitting corrosion
β Scribed by A. M. Shams El Din; M. M. Badran; S. E. Khalil
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- German
- Weight
- 452 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0947-5117
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β¦ Synopsis
Abstract
The pitting susceptibility of stainless steels with (%) 17.39 Cr, 5.3 Ni, 0.3β13.9 Mn in chloride solutions have been studied by a potentiodynamic cyclic polarization technique in solutions 0.1 N H~2~SO~4~ + 0.9 N Na~2~So~4~ + various amounts of NaCl. At low NaCl concentrations no pronounced influence of the chloride can be found and even at medium concentrations the passivation behaviour is generally maintained; in this region, however, there is an increase of dissolution and passivation current densities. High chloride concentrations, however, result in pitting which may be completely suppressed by a cyclic (anodic/cathodic) polarization technique. As to pitting resistance an alloy containing (%) 17.3 Cr, 5.3 Ni, 5.6 Mn is comparable to the steel CrNi 18 9.
π SIMILAR VOLUMES
During the past few years, biomineralized manganese has been shown to cause ennoblement of various stainless steels to open circuit potentials of 300 Β± 400 mV/SCE. We have demonstrated that ennoblement, caused by biologically deposited manganese minerals, along with a relatively low stainless steel