Corrinoid catalysis of thiol oxidation

✍ Scribed by D.W. Jacobsen

• Book ID: 104137881
• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 323 KB
• Volume: 79
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)95225-3

✦ Synopsis

1.999(6) A, Fe-N(N0) = 1.652(S) A, and Fe-O = 2.001(5)

A. For [Fe(OEP)(NO)]C104 (Fig. l), Fe-N, = 1.994(l) A, Fe-N(N0) = 1.644(3) A; the iron(III) atom is displaced 0.29 A from the mean plane of the porphinato core. The structural parameters of both complexes are appropriate for low-spin ferric porphyrinates.

[Fe(OEP)(NO)] C104 forms a remarkable n-n dimer in the solid state (Fig. 2). The two planar cores are parallel with an interplanar separation of only 3.36 A.