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Peracetic Acid Oxidation of Thiol Esters

โœ Scribed by Cavallito, Chester J.; Fruehauf, Dorothy McKenica.

Book ID
120178906
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
225 KB
Volume
71
Category
Article
ISSN
0002-7863

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Thiol eaters, important in the bioryntheeia of fatty acida, have been shown to be much more acidic than eaters(l). In order to rationalize the large difference in acidities, Cronyn and co-workers(2) proposed that the eater anion would be greatly destabilized relative to an a-keto carbanion because