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Corrigendum to “Towards the synthesis of (+)-discodermolide”: [Tetrahedron Lett. 42 (2001) 4713–4716]

✍ Scribed by J.S. Yadav; Sunny Abraham; M.Muralidhar Reddy; Gowravaram Sabitha; A.Ravi Sankar; A.C. Kunwar


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
85 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


The authors regret that the structures of 14-17 in Scheme 3 have been drawn incorrectly. The corrected Scheme is shown below. Scheme 3. (a) LAH, THF, 0°C-rt, 4 h; (b) TBDPS-Cl, imidazole, DCM, 0°C-rt, 2 h; (c) DEAD, TPP, p-NO 2 C 6 H 4 -COOH, THF, 0°C-rt; (d) Dess-Martin periodinane, DCM, rt, 2 h; (e) NaBH 4 , MeOH/THF, 0°C-rt, 1 h; (f) TBAF, THF, rt, 1.5 h; (g) IBX, DMSO/DCM, rt, 6 h; (h) NaCNBH 3 , MeOH/AcOH, pH 5.5, rt, 1 h; (i) TBDMS-Cl, imidazole, DCM, 0°C-rt, 1.5 h; (j) 1% NaOH, THF, 3 h, H + , CH 3 COONa, Ac 2 O, warm, 5 min.


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