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Corrigendum to “Synthesis of 4-demethoxyadriamycinone utilizing ruthenium-catalyzed oxidation of allyl acetates”: [Tetrahedron Lett. 42 (2001) 3343–3346]

✍ Scribed by Torsten Hotopp; Hans-Jürgen Gutke; Shun-Ichi Murahashi

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
25 KB
Volume
43
Category
Article
ISSN
0040-4039

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Synthesis of 4-demethoxyadriamycinone ut
Synthesis of 4-demethoxyadriamycinone utilizing ruthenium-catalyzed oxidation of allyl acetates
✍ Torsten Hottop; Hans-Jürgen Gutke; Shun-Ichi Murahashi 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 67 KB

A new method for the construction of the side chain of anti-cancer drugs adriamycins is demonstrated by the synthesis of 4-demethoxyadriamycinone. The key step is the ruthenium-catalyzed oxidation of allyl acetates to the corresponding a-hydroxyketones.