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ChemInform Abstract: Synthesis of 4-Demethoxyadriamycinone Utilizing Ruthenium-Catalyzed Oxidation of Allyl Acetates.

✍ Scribed by Torsten Hottop; Hans-Juergen Gutke; Shun-Ichi Murahashi

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis of 4-demethoxyadriamycinone ut
Synthesis of 4-demethoxyadriamycinone utilizing ruthenium-catalyzed oxidation of allyl acetates
✍ Torsten Hottop; Hans-JΓΌrgen Gutke; Shun-Ichi Murahashi πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 67 KB

A new method for the construction of the side chain of anti-cancer drugs adriamycins is demonstrated by the synthesis of 4-demethoxyadriamycinone. The key step is the ruthenium-catalyzed oxidation of allyl acetates to the corresponding a-hydroxyketones.

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