Correlation-type structure activity relationships for the kinetics of gas-phase RO2 self-reactions and reaction with HO2
β Scribed by David Johnson; David W. Price; George Marston
- Book ID
- 113475413
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 264 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1352-2310
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm
Rate coefficients have been determined for the reaction of butanal and 2-methylpropanal with NO 3 using relative and absolute methods. The relative measurements were accomplished by using a static reactor with long-path FTIR spectroscopy as the analytical tool. The absolute measurements were made us