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Correlation of the tautomeric equilibrium ofα-substituted acetoacetic esters with the polar constants of the substituents

✍ Scribed by S. T. Ioffe; M. I. Kabachnik

Book ID
112419929
Publisher
Springer
Year
1966
Tongue
English
Weight
118 KB
Volume
15
Category
Article
ISSN
1573-9171

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Linear correlation of polar substituents
Linear correlation of polar substituents in the gas-phase pyrolyses of ethyl α-substituted acetates
✍ Alexandra Rotinov; Gabriel Chuchani 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

The pyrolysis kinetics of several ethyl esters with polar substituents at the acyl carbon have been studied in the temperature range of 319.8-400.0"C and pressure range of 50.5-178.0 tom. These eliminations are homogeneous, unimolecular, and follow a first-order rate law. The rate coefficients are g