Correlation of chemical shifts δ(OH) and ionization constants pKaof substituted phenols with the constants of the substituents
✍ Scribed by O. N. Karpov; T. N. Pliev
- Publisher
- Springer US
- Year
- 1975
- Tongue
- English
- Weight
- 578 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0021-9037
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Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o
## Abstract Heats of formation and net atomic charges of some 120 structures involving substituted phenols, anilines, and benzoic acids and the corresponding anions were calculated by MNDO, AM1, and PM3 semiempirical methods. The gas phase acidities of substituted phenols and anilines and the net a