Ham&t wsubstituent constant is a measure of the effect of the substituent on the activation energy of the reaction of the unsubstituted cowpoundw or it "measures the effect of the substituent on the electron density at the reaction site".' The change in halogenobenzenes nuclear quadrupole resonance
β¦ LIBER β¦
Correlation of the nuclear quadrupole resonance frequencies with X taft constants
β Scribed by E.N. Tsvetkov; G.K. Semin; D.I. Lobanov; M.I. Kabachnik
- Book ID
- 104224030
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 247 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The correlations between the nuclear quadrupole resonance (NQR) freqU-.encies and constants characterizing the electron influence of substituents I,2 , are for different reasons (poor accuracy or being of restricted use), valid only in some cases.
Recently we have shown3 that there exists an approximately linear rela-
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