Correlation of spin-spin coupling constants with electronic displacements in organo-mercury compounds
✍ Scribed by L. A. Fedorov; É. I. Fedin; B. A. Kvasov; I. P. Beletskaya
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1969
- Tongue
- English
- Weight
- 395 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-4766
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## Abstract A series of alicyclic compounds with dihedral angles of 0°, 60°, 90°, 120° and 180° between a ^13^C‐labelled carbon atom and a carbon atom separated by three bonds from the label has been synthesized. The vicinal ^13^C^13^C spin coupling constants were measured, and from the results a K
A linear function correlates the 13C-H nuclear spin-spin coupling constant J (in c.p.s.) and the fractional s-character (p,) of the carbon 8.0. from which the C-H bond is formed': Recently Foote\* has reported that J in cycloelkcmes appears to be related to the internuclear C-C-C bond sngle 0, by 2