The potential energy surfaces for the proton transfer processes in H+(H20), with n = 2 -11 have been studied using the semiempirical AM^ method. Two model systems were adopted branched and linear systems. The branched system showed a tendency to form a bulk cluster, while the linear system showed a
Correlation effects on energy curves for proton transfer. The cation [H5O2]+
β Scribed by Wilfried Meyer; Werner Jakubetz; Peter Schuster
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 449 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The chemiluminescence of the luminol-H 2 O 2 -horseradish peroxidase system is increased by fluorescein. Fluorescein produces an enhancement of the luminol chemiluminescence similar to that of phenolphthalein, by an energy transfer process from luminol to fluorescein. The maximum intesity and the to
A study of eschange sir&t-singlet energy transfer was made between a series of stcrically hindered ketones end a-diketones in fluid cyclohesane. The comparison of the measured rate constants of energy transfer shows them to be nearly diffusion controlled and insensitive to stcric hindrance. This is