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Correlation between the rate constants of S-T and T-S intersystem crossing in aza- and diazaphenanthrenes

โœ Scribed by L. I. Korshunov; V. D. Shatrov; V. S. Kuznetsov; V. F. Rachek; Yu. A. Mikhailov; I. G. Batekha; A. V. El'tsov

Publisher
Springer US
Year
1980
Tongue
English
Weight
434 KB
Volume
33
Category
Article
ISSN
0021-9037

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๐Ÿ“œ SIMILAR VOLUMES

A comparison of the rate constants for i
A comparison of the rate constants for intersystem crossing via S1(ฯ€,ฯ€*) T(ฯ€,ฯ€*) and S1(n,ฯ€*) T(ฯ€,ฯ€*) paths
โœ H. Dewey; S.G. Hadley ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 291 KB

The rate constants for S1 -T intersystem crossing have been deWmined for rigid glass solutions of phenant!!ne and 9,lOdiazaphenanthrene at the temperature of boiling nitroger;. For phenanthrene intersystem crossing path is Sl(n,n\*) -T(~.z\*) where kiscw~ found to be (4.8 + 1) X 106.sec:1. For 9,Khi

Contribution of S0 โ†” Tยฑ1 intersystem cro
Contribution of S0 โ†” Tยฑ1 intersystem crossing in radical pairs to chemically induced nuclear and electron spin polarizations
โœ F.J. Adrian ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 454 KB

It is found that intersgstem crossings between the singlet and the MS = fl components of the triplet state of radical p&in liquids can produce nuclear and electron spin polarizations when two radicals diffuse apart follOWing arl initial encounter and subsequently undergo a second nonreactive encount