Correlation between electron capture response and chemical structure for alkyl halides
β Scribed by Kojima, Tsugio.; Tanaka, Yasukazu.; Satouchi, Masaru.
- Book ID
- 127171853
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 377 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0003-2700
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π SIMILAR VOLUMES
Correlationbse tween molecular structure and fragmentation observed in electron capture negative chemical ionization mass spectra (moderator gas = methane) of 49 selected tetrachlorinated, pentachlorinated, and hexachlorinated biphenyls have been investigated by using molecular modeling. The semiemp
I t is shown that cyclic oxides can be anionically polymerized if the lowest vacant molecular orbital (LVMO) of a C, atom contains a region which can effectively overlap by the electronic cloud of the anionic active centre. This means that LVMO must be a-symmetrical and a t least one of the C, atoms