Distinguishing between polar and electron-transfer mechanisms for reactions for anions with alkyl halides
โ Scribed by Bordwell, F. G.; Wilson, Craig A.
- Book ID
- 127200520
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 666 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Evidence for a radical process in' the reaction of lithium alkoxides with alkyl iodides was obtained by the observation of cyclization of appropriate radical probes, by the trapping of radicals, and by EPR spectroscopic observations relating to the one electron donor properties of alkoxides.
The reaction of the hromo-substituted naphthalene 1 with the alkanethiolate anions 2a-b and arenethiolate 2c in tetraglyme gave the corresponding 1 -naphthyl thio-ethers 3a\*. Thio-ethers 3a-e were oxidized to the corresponding sulfones 4a\* with m-chloroperoxybenzoic acid. The reaction of the dichl