The Ebel Model, which characterizes a sample consisting of a thin carbonaceous overlayer on a substrate of a different material, provides a relationship between the carbon 1s and Auger peak intensities and the overlayer thickness. In this paper, Ebel model predictions for six substrate materials (si
Correction for the effects of adventitious carbon overlayers in quantitative XPS analysis
β Scribed by Evans, Stephen
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 258 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0142-2421
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β¦ Synopsis
A data processing procedure is described that enables the energy-dependent attenuation of the substrate XPS signals from typical samples exhibiting adventitious carbon contamination to be objectively and quantitatively compensated when obtaining elemental analyses from the XPS peak intensities. The procedure is based on wellestablished theory for a uniform overlayer on a homogeneous substrate, and is evaluated using two representative substrates : oxidized sheet zinc and pressed pellets of sodium Γuoride. Suitable values for key parameters are recommended, and an application program in MS-DOS Q-BASIC is available via the Internet.
1997 John ( Wiley & Sons, Ltd.
π SIMILAR VOLUMES
A new method is proposed to correct for attenuation effects by adventitious organic contamination in quantitative XPS. The corrected intensity ratio I o X =I o Y involving two different substrate peaks is determined as the slope of the plot of I X =I C1s as a function of I Y =I C1s for samples cover
Elastic electron scattering in XPS and AES vary considerably with depth of origin of emitted electrons. To account for this, we introduced in a recent paper a simple correction factor CF. The function CF is the ratio of emitted peak intensity from a layer of atoms located at a given depth in a solid