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Coriolis Interactions in the ν2, ν4a, ν4b, and ν3aStates of Phosphine-d1

✍ Scribed by R.J. Kshirsagar; V.A. Job

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
288 KB
Volume
185
Category
Article
ISSN
0022-2852

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✦ Synopsis

Spectra of the n 4a (HPH bend) and n 4b (HPD bend) bands of the PH 2 D molecule have been recorded and analyzed. The Coriolis interactions between the two states as well as the various Coriolis interactions of the n 4a and n 4b states with the n 2 state have been included in the analysis. Several new assignments of transitions which occur with enhanced intensity in the n 2 band also have been made. The parameters of the n 4a and n 4b states, improved parameters of the n 2 state, and the interaction parameters have been determined. The data on the n 3a band of PH 2 D have been reanalyzed by taking into account the b-axis Coriolis interaction of the n 3a state with the 2n 2 state.

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