Copper(II), nickel(II) and iron(II) complexes of 2,6-diacetylpyridine bis{[dl-hydroxy(phenyl)acetic]hydrazone}. X-ray structure of a 1:2 metal:ligand nickel complex
β Scribed by Alex Bonardi; Sandra Ianelli; Corrado Pelizzi; Giancarlo Pelizzi; Costantino Solinas
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 535 KB
- Volume
- 232
- Category
- Article
- ISSN
- 0020-1693
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The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act
The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur