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Syntheses, Characterization and Reactivity of Iron(II), Nickel(II), Copper(II) and Zinc(II) Complexes of the Ligand N,N,N′,N′-Tetrakis(2-pyridylmethyl)benzene-1,3-diamine (1,3-tpbd) and Its Phenol Derivative 2,6-Bis[bis(2-pyridylmethyl)amino]-p-cresol (2,6-tpcd)

✍ Scribed by Simon Foxon; Jing-Yuan Xu; Sabrina Turba; Michael Leibold; Frank Hampel; Frank W. Heinemann; Olaf Walter; Christian Würtele; Max Holthausen; Siegfried Schindler


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
391 KB
Volume
2007
Category
Article
ISSN
1434-1948

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## Abstract The dinuclear copper(II) complexes {[Cu~2~(1,3‐tpbd)(H~2~O)(OAc)~2~](ClO~4~)~2~}~0.23~{[Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)](ClO~4~)~3~}~0.77~·0.77H~2~O (1), [Cu~2~(1,3‐tpbd)(H~2~O)~2~(OAc)~2~](ClO~4~)~2~·2H~2~O (2), and the tetranuclear copper(II) complex [Cu~4~(1,3‐tpbd)~2~(H~2~O)~2~(SO~4~

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## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t

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The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur