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Copper(II)-histidine stereochemistry. Structure of L-histidinato-D-histidinatodiaquocopper(II) tetrahydrate

✍ Scribed by Camerman, N.; Fawcett, J. K.; Kruck, T. P. A.; Sarkar, B.; Camerman, A.

Book ID
127056144
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
503 KB
Volume
100
Category
Article
ISSN
0002-7863

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The title complex has a mononuclear structure, [Cu(C 10 H 12- NO 3 ) 2 ]Á4H 2 O, which is a centrosymmetric unit with both d and l-sala ligands [sala = N-(4-hydroxybenzyl)alanine] coordinated to the Cu II center. Hydrogen bonding results in a threedimensional supramolecular structure.