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Bis­[N-(4-hydroxy­benzyl)-d,l-alaninato]copper(II) tetrahydrate

✍ Scribed by Lou, Ben-Yong ;Xu, Ying ;Yuan, Da-Qiang ;Han, Lei ;Hong, Mao-Chun

Book ID
104481756
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
299 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex has a mononuclear structure, [Cu(C 10 H 12- NO 3 ) 2 ]Á4H 2 O, which is a centrosymmetric unit with both d and l-sala ligands [sala = N-(4-hydroxybenzyl)alanine] coordinated to the Cu II center. Hydrogen bonding results in a threedimensional supramolecular structure.

📜 SIMILAR VOLUMES

Diaqua­[N-(3-carb­oxy-2-hydroxy­benzyl­i
Diaqua­[N-(3-carb­oxy-2-hydroxy­benzyl­idene)alaninato-κ3O2,N,O′]copper(II) dihydrate
✍ Yu, Zhao-Wen ;Hao, Yun-Ling ;Zhang, Wu ;Cui, Qing-Xia 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

In the crystal structure of the title compound, [Cu(C 11 H 9 -NO 5 )(H 2 O) 2 ]Á2H 2 O, in which N-(3-carboxy-2-hydroxybenzylidene)alaninate (H 3 ALS) is the Schiff base synthesized from l-alanine with 3-carboxysalicylaldehyde, the copper(II) ion is pentacoordinated in a square-pyramidal geometry, w

Bis­{(Z)-N′-(2,4-dichloro­benzyl­idene)-
Bis­{(Z)-N′-(2,4-dichloro­benzyl­idene)-2-hydroxy­benzohydrazide-κ2N′,O}bis(pyridine-κN)cobalt(II). Corrigendum
✍ Qiu, Xiao-Yang ;Yang, Sen-Lin ;Liu, Wei-Sheng ;Zhu, Hai-Liang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

In the original paper by Qiu, Yang, Liu & Zhu [__Acta Cryst.__ (2006), E**62**, m1320–m1231], the H atoms attached to N1 and N3 are positioned incorrectly. These have been deleted and the structure rerefined. The correct name of the structure is bis(2,4-dichlorobenzaldehyde 2-hydroxybenzoylhydrazona