A facile synthetic route to mercaptyl functionalized b-cyclodextrins was devised and self-assembled onto the gold electrodes of a quartz crystal microbalance (QCM) to afford a durable sensor capable of chiral discrimination of enantiomers.
Copper(II) assisted self-Assembly of functionalized β-Cyclodextrins with β-Alanyl-l-histidine
✍ Scribed by Diego La Mendola; Placido Mineo; Enrico Rizzarelli; Emilio Scamporrino; Graziella Vecchio; Daniele Vitalini
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 174 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1472-7862
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✦ Synopsis
A combined UV-visible, CD and ESI-MS spectroscopic approach has been followed to obtain the speciation and the bonding details of copper(II) complexes with b-cyclodextrins functionalized by means of the bio-active peptide b-alanyl-l-histidine (carnosine). A new metal-assisted self-assembled system of bifunctionalized b-cyclodextrins has been shown to exist.
📜 SIMILAR VOLUMES
Progress toward the synthesis of guanine-cytosine (GKC) oligonucleotides for the spontaneous selfassembly of rosette nanotubes (RNTs) with predefined length is described. Highlighted is the synthesis of the b-glycoside functionalized GKC base along with a new nitrogen protecting group strategy that