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Copper(I) tert-butoxide-promoted stereospecific alkylation of β-hydroxymethylvinylsilanes with alkyl halides

✍ Scribed by Haruhiko Taguchi; Akira Tsubouchi; Takeshi Takeda

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 336 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01251-6

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✦ Synopsis

Stereospecific alkylation of (Z)-b-hydroxymethylvinylsilanes proceeded by treatment with copper(I) tert-butoxide and alkyl halides. Tri-and tetra-substituted allylic alcohols were obtained with complete retention of configuration.

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