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Copper(I) tert-Butoxide-Promoted Stereospecific Alkylation of β-Hydroxymethylvinylsilanes with Alkyl Halides.

✍ Scribed by Haruhiko Taguchi; Akira Tsubouchi; Takeshi Takeda


Publisher
John Wiley and Sons
Year
2003
Weight
92 KB
Volume
34
Category
Article
ISSN
0931-7597

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Copper(I) tert-butoxide-promoted stereos
✍ Haruhiko Taguchi; Akira Tsubouchi; Takeshi Takeda 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 336 KB

Stereospecific alkylation of (Z)-b-hydroxymethylvinylsilanes proceeded by treatment with copper(I) tert-butoxide and alkyl halides. Tri-and tetra-substituted allylic alcohols were obtained with complete retention of configuration.