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Copper(I)-Fesulphos Lewis Acid Catalysts for Enantioselective Mannich-Type Reaction of N-Sulfonyl Imines

✍ Scribed by González, Alvaro Salvador; Arrayás, Ramón Gómez; Carretero, Juan C.

Book ID: 111861414
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 79 KB
Volume: 8
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol060866v

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## Abstract **Mild mannered!** A highly diastereo‐ and enantioselective Mannich‐type reaction of glycine Schiff base **1** has been developed by using the __N,N′__‐dioxide **L**‐Cu^II^ complex as a catalyst. Various optically active __anti‐__α,β‐diamino acid esters were obtained in good yields with