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Copper(I)-Fesulphos Lewis Acid Catalysts for Enantioselective Mannich-Type Reaction of N-Sulfonyl Imines.

✍ Scribed by Alvaro Salvador Gonzalez; Ramon Gomez Arrayas; Juan C. Carretero


Publisher
John Wiley and Sons
Year
2006
Weight
37 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Deju Shang; Yanling Liu; Xin Zhou; Xiaohua Liu; Xiaoming Feng 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB 👁 2 views

## Abstract **Mild mannered!** A highly diastereo‐ and enantioselective Mannich‐type reaction of glycine Schiff base **1** has been developed by using the __N,N′__‐dioxide **L**‐Cu^II^ complex as a catalyst. Various optically active __anti‐__α,β‐diamino acid esters were obtained in good yields with