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Copper(I)-Catalyzed Amination of Aryl Halides in Liquid Ammonia

✍ Scribed by Ji, Pengju; Atherton, John H.; Page, Michael I.


Book ID
115461668
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
496 KB
Volume
77
Category
Article
ISSN
0022-3263

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Efficient Copper-Catalyzed Direct Aminat
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## Abstract The __N^2^,N^2^β€²__‐diisopropyloxalohydrazide/CuO system efficiently catalyzed the direct amination of aryl bromides andiodides with aqueous ammonia in water at 60 Β°C in 24 h or at 120 Β°C in only 20–30 min. Both activated and unactivated aryl and heteroaryl bromides and iodides were read