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Copper(I) catalysis: Synthesis of N,N′-diarylated and N-aryl,N′-formylated chiral C2-symmetric diamines

✍ Scribed by Laxhmaiah Alakonda; Mariappan Periasamy


Book ID
118475752
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
561 KB
Volume
694
Category
Article
ISSN
0022-328X

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Efficient synthesis of chiral C2-symmetr
✍ P. Veeraraghavan Ramachandran; Debanjan Biswas; Marek P. Krzeminski; Guang-Ming 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 425 KB

An enantioselective synthesis of C 2 -symmetric bis-homoallylic aromatic and heteroaromatic diamines in 54-89% yields, in 73-94% de and P98% ee has been achieved via the allylboration of the corresponding N,N 0 -bis(trimethylsilyl)dialdimines and N,N 0 -bis(diisobutylalumino)dialdimines with B-allyl