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Copper(I) and copper(II) in complexes of biochemical significance studied by X-ray photoelectron spectroscopy

โœ Scribed by Heinz Rupp; Ulrich Weser

Book ID
113125131
Publisher
Elsevier Science
Year
1976
Weight
789 KB
Volume
446
Category
Article
ISSN
0005-2795

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X-ray photoelectron spectroscopy using copper( copper(I) and the mixed valence Cu(II)/Cu(i) compounds was empIoyed as a means of studying electron transfer reactions in copper proteins\_ The X-ray photoelectron spectra of copper(i1) compounds display characteristic satellites of both variable sire a

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## The X-ray photoelectron spectra of the anhydrous copper(I) and copper(U) carboxylates Cu(O,CR), (R = Me, Et, Pr", Ph; n = 1 and 2), have been investigated and the copper 2p,,, and 2~~~~ and carbon 1s binding energies measured. An apparent correlation of copper 2p binding energies with metal oxida