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Copper—Dioxygen Complexes and Their Roles in Biomimetic Oxidation Reactions.

✍ Scribed by Christiana Xin Zhang; Hong-Chang Liang; Kristi J. Humphreys; Kenneth D. Karlin

Publisher
John Wiley and Sons
Year
2003
Weight
57 KB
Volume
34
Category
Article
ISSN
0931-7597

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✍ Li Mi; Andreas D. Zuberbühler 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 471 KB

## Abstract The copper‐catalyzed oxidation of ascorbic acid (AscH~2~) has been studied with a __Clark__ electrode in aqueous MeCN. Cu^I^ or Cu^II^ may be equally used as the source of metal ion, without influence on the rate law. At sufficiently high [MeCN], the rate of the overall reaction is esse