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Copper Triflate as a Catalyst in Atom Transfer Radical Polymerization of Styrene and Methyl Acrylate

✍ Scribed by Woodworth, Brian E.; Metzner, Zack; Matyjaszewski, Krzysztof

Book ID
118022992
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
72 KB
Volume
31
Category
Article
ISSN
0024-9297

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## Abstract Summary: The homogeneous bulk reverse ATRP using AIBN/Cu(SC(S)N(C~4~H~9~)~2~)~2~/bpy as the initiating system has been successfully carried out for methyl methacrylate. Well‐controlled polymerizations with low polydispersities ($\overline M \_{\rm w} /\overline M \_{\rm n}$ = 1.10–1.30)