𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Copper-Free Asymmetric Allylic Alkylation with a Grignard Reagent: Design of the Ligand and Mechanistic Studies

✍ Scribed by Grassi, David; Dolka, Chrysanthi; Jackowski, Olivier; Alexakis, Alexandre


Book ID
118754194
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
523 KB
Volume
19
Category
Article
ISSN
0947-6539

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Nickel-catalyzed asymmetric allylation o
✍ Nobuyoshi Nomura; T.V. RajanBabu πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 252 KB

Enantioselective addition of Griguard reagents to methyl 1,3-diphenylallyl ether in the presence of Ni(0)-phosphine catalysts is reported. Kinetic resolution (79 %Β’e) observed in the addition of MeMgBr has important implications for the mechanism and further development of this reaction as a valuabl